Miceller catatysis and its effect upon dephosphorylation of 2-Methoxy phenyl phosphoramides by peroxy anions in buffer medium
Ravi Prakash, R B Singh
Micellar catalysed reactions between hydroxide or hydroperoxide anions and diphosphate ester of 2-MPPA has been examined in buffered medium at pH 8 to 10 with borate ions. First order rate constant (K) for the reaction of OH- ion with 2-MPPA go through maxima with increasing the concentration of cetyltrimethyl ammonium-bromide (CTABr). Micelles of CTABr are very effective catalysts to the reactions of 2- methoxy phenyl phosphoramide. Rate enhancement depends upon the hydrophobicity of the nucleophile for the reactions of 2- methoxy phenyl phosphoramide. Rate constants measured with ions are approximately twice and thrice than that of OH- ions in presence of CTABr It has been known much early about the importance of organic phosphate esters as phospholipids, complex lipids as fatty acid esters containing phosphorus, nitrogen bases or sugars which have been described to spherical, helical and folded laminar type micelles. Many phospholipids exist in both and forms as well as different stereo chemical configurations which can be isolated in phospholipids, diollipids and sphingolipids. An extensive amount of research carried out in recent years on chemical model system for specific enzymatic interactions, similarities between nonionic micelles and globular proteins render micelles potentially useful as model for investigation of hydrophobic interaction. The micellar catalysis in all biochemical reactions may provide a basic model for interpretation for some aspects of metabolic process undergoing biochemical change in the body pass through biogenesis of different types of natural surfactants. Since it is the easiest organism to handle in development of DNA to produce new organism in plants and flowers by fusing a particular gene to produce new DNA molecules. The most popular types of paste, cream, shampoo are currently employing sodiumlaurylsulphate as the detergent and sodiumstreate as the opacifying cream foaming agent and the thickening agents. Low molecular weight, cationic agents and detergent of the type have been used. Detergent to be use in tooth past must be specially purified and certified and inherently non-toxic. The cationic surface active agents for such diverse designificating purpose of designification in military and naval establishments, sterilization of instruments and skin surgery.
Ravi Prakash, R B Singh. Miceller catatysis and its effect upon dephosphorylation of 2-Methoxy phenyl phosphoramides by peroxy anions in buffer medium. International Journal of Advanced Scientific Research, Volume 6, Issue 6, 2021, Pages 6-8